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Beilstein J. Org. Chem. 2012, 8, 994–1002, doi:10.3762/bjoc.8.112
Graphical Abstract
Figure 1: Super-electron-donors and related compounds.
Scheme 1: Preparation of the oxidised disalts.
Figure 2: Cyclic voltammograms in DMF of 8/4 (red) and 21/11 (blue). Current plotted vs V (relative to Fc/Fc+...
Scheme 2: Reductive reactions of donor 11 [17,18].
Figure 3: Cyclic voltammograms in DMF of 8/4 (red), 6/1 (green) and 22/9 (blue). Current plotted vs V relativ...
Scheme 3: Reductive reactions of donor 9.
Figure 4: (a) c.v. in DMF of 7/2 (red), 6/1 (green) and 27/10 (blue); (b) c.v. in DMF of 27/10 at different s...
Scheme 4: Use of hybrid donor 10 in reduction of iodoarenes.
Scheme 5: Reductive chemistry from disalt 15.
Scheme 6: Rationalisation of effect of excess NaH base.